*The production of iron requires three important raw materials: iron ore, coal converted to "coke", and limestone.
Following are the stages where the CO can be evolved during iron making process:
**The coal is converted to a product called coke in coking ovens. The three raw materials are added to the top of the blast furnace. A blast of air containing oxygen is forced in from the bottom of the furnace. This causes the coke to burn with an intense heat of almost 2000 C. The reaction is carbon plus oxygen to produce carbon monoxide (incomplete combustion due to lack of air).
2C + O2 = CO
**The main reaction is then between the iron oxide, Fe2O3, with the carbon monoxide to produce molten iron metal and carbon dioxide. An alternate reaction is with the coke, C, to produce iron and more carbon monoxide. The molten iron collects on the bottom of the furnace and when cooled is called pig iron with many impurities.
Fe2O3+3C=2Fe+3CO
**Much of the carbon dioxide is reduced with more carbon from the coke to make more carbon monoxide.
**
1.At the high temperature at the bottom of the furnace, carbon dioxide reacts with carbon to produce carbon monoxide.
C +CO2=2CO
2.In the hotter parts of the furnace, the carbon itself also acts as a reducing agent. Notice that at these temperatures, the other product of the reaction is carbon monoxide, not carbon dioxide.
*Pl. go through following link:
http://www.chemguide.co.uk/inorganic/extraction/iron.html